Hitachi CHROMASTER 5160 Instruction Manual page 337

Polarity
2
E (Al O
2
Fluoroalkanes -0.25
0.00
n-Pentane
Hexane 0.00
Isooctane 0.01
Petroleum ether 0.01
n-Decane 0.04
Cyclohexane 0.04
Cyclopentane 0.05
0.06
Diisobutylene
i-Pentane 0.08
Carbon disulfide 0.15
Carbon tetrachloride 0.18
Amyl chloride 0.26
Butyl chloride 0.26
Xylene 0.26
i-Propyl ether 0.28
i-Propyl chloride 0.29
Toluene 0.29
0.30
n-Propyl chloride
Chlorobenzene 0.30
Benzene 0.32
Ethyl bromide 0.37
Ethyl ether 0.38
Ethyl sulfide 0.38
Chloroform 0.40
Methylene chloride 0.42
Methyl i-butyl ketone 0.43
Tetrahydrofurane 0.45
Ethylene dichloride 0.49
Methyl ethyl ketone 0.51
i-Nitropropane 0.53
0.56
Acetone
Dioxane 0.56
Ethyl acetate 0.58
Methyl acetate 0.60
Amyl alcohol 0.61
Dimethyl sulfoxide 0.62
0.62
Aniline
0.63
Dimethyl amine
Nitromethane 0.64
Acetonitrile 0.65
Pyridine 0.71
Butyl cellosolve 0.74
i-Propanol n-Propanol 0.82
0.88
Ethanol
Methanol 0.95
Ethylene glycol 1.11
Acetic acid Large
Water Large
Salts & buffer Larger
* L. R. Snydar, Dekker. "Principles of Adsorption
Chromatography"
Kagaku Benran (handbook of chemistry) - Basics,
†
2nd revision authored by The Chemical Society of
Japan.
Table 3-2 Characteristics of Organic Solvents
Refrac- UV
Viscosity
tive Cutoff
) (cP20°C)
3
Index (nm)
1.25
0.23 210
1.358
1.375 210
1.404 210
0.3 210
0.92 1.412
1.00
1.427 210
0.47 210
1.406
1.411 210
1.371
0.37 1.626 380
0.97 1.466 265
0.43
1.413 225
1.436 220
†
0.81
†
0.61 ~1.50 290
†
0.64
1.368 220
0.37 1.378 225
0.33 1.496 285
225
0.59 1.389
0.35 1.525
0.80 1.501 280
0.65 1.424
1.353 220
0.23 1.442 290
245
0.45 1.443
1.424 245
0.57
0.44 1.394 330
1.408 220
1.445 230
0.79 1.381 330
1.400 380
1.359 220
1.422 260
0.32
1.54 1.370 260
0.45 1.362 210
0.37 1.410
4.1
2.24 1.586
1.387 275
4.4
0.38 1.394 380
0.67 1.344 210
0.37 1.510 305
0.94 220
210
1.38
210
2.3 1.361
1.329 210
1.20
0.60 1.427 210
19.9 1.372
1.26 1.333
Ignition Point
Flash
Point
Lower
(°C)
(°C)
Limit
<-40 1.5
308.9
-21.7 233.9 1.2
46.1 207.8 0.8
-20 1.3
260
-17.8 272.8 1.5
-30 100 1.3
12.8
343.3 1.6
-9.4 460 1.8
463.9 1.0
o-17.2
m-25 527.8 1.1
p-25 528.9 1.1
-27.8 443.3 1.4
-32.2 593.3 2.8
4.4 536.1 1.4
2.6
<-17.8
32.2 637.8 1.3
-11.1 562.2 1.4
511.1 6.7
-45 180 1.9
518.9 3.8
-50
-14.4 321.1 2
13.3 412.3 6.2
-6.1 515.6 1.8
2.6
48.9 420.6
537.8 2.6
-17.8
180 2.0
12.2
4.4 460 1.8
-10 501.7 3.1
32.8 300 1.2
1.3
70 617.2
312.2 1.8
<-17.8
35 418.3 7.3
5.6
20 1.8
2.0
11.7 398.9
422.8 4.3
12.8
11.1 463.9 7.3
111.1 412.8 3.2
The solvents having a low
boiling point enclosed by bold
line cannot be used.
3 - 55
Vapor Boiling
Density Point
Upper
(air = 1) (°C)
Limit
2.5 36.1
7.8
7.5 3.0 68.9
5.4 4.9 173.9
8 2.9 81.7
8.7 2.4 30
44 2.6 46.1
8.6 3.7 106.1
10.1 3.2
6.0 144.4
7.0 3.7 138.9
7.0 138.3
21 3.5 68.9
10.7 2.7 35
6.7 3.1 110.6
2.7
11.1 46.1
7.1 3.9
132.2
7.1 2.8 80
11.3 3.8 37.8
48 2.6 35
15.4 2.2
38.5
11.8 2.5 66.1
16 3.4 83.9
10 2.5 80
3.1 131.1
2.0
12.8 56.7
22 3.0
101.1
8 3.5 90
16 2.6 60
10.0 3.0 137.8
3.2
184.4
2.5
10.1 56.7
2.1 101.1
1.4 81.7
12.4 2.7 115
12 2.1 82.8
1.6
19 78.3
36 1.1
63.9
197.2
3.6.2
Specific
Gravity
(water =
1)
0.6
0.7
0.7
0.8
0.7
1.3
0.9
0.9
0.9
0.7
0.9
0.9
0.9
1.1
0.9
1.4
0.7
0.9
0.9
1.3
0.8
1.0
0.8
1.0
0.9
0.9
0.8
1.0
0.7
1.1
0.8
1.0
0.8
0.8
0.8
1.1