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BMT MESSTECHNIK GMBH
OZONE ANALYZER BMT 965
Manual
(Rev. 01/2024)
BMT MESSTECHNIK GMBH, Stahnsdorf, Germany.
www.bmt-berlin.de Tel. +49 - 3329 - 696 77 - 0, sales@bmt-berlin.de
OSTI, COLORADO, USA
www.osti-inc.com Tel. +1 - 831 - 649 - 11 41, sales@osti-inc.de

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  • Page 1 BMT MESSTECHNIK GMBH OZONE ANALYZER BMT 965 Manual (Rev. 01/2024) BMT MESSTECHNIK GMBH, Stahnsdorf, Germany. www.bmt-berlin.de Tel. +49 - 3329 - 696 77 - 0, sales@bmt-berlin.de OSTI, COLORADO, USA www.osti-inc.com Tel. +1 - 831 - 649 - 11 41, sales@osti-inc.de...
  • Page 2: Table Of Contents

    This manual describes the standard version BMT 965 ST. For the versions BMT 965 BT, BMT 965 C, BMT 965 OG, BMT 965 AQ and BMT 965 RD, also refer to the according Ap- pendices at the end of this manual!
  • Page 3 The Serial Interface User-Mode Link-Mode File Operations and the USB Interface Connecting a Windows Computer to the BMT 965 Connecting a USB Flash Drive to the BMT 965 Firmware Upgrade Error Handling and Early Warnings Lamp Low Warning Lamp Low Error...
  • Page 4 Specifications (BMT 965 AQ only) Appendix F: Remote Display BMT 965 RD General Description Operation Appendix G: IP-based Communication BMT 965 C / OG / AQ – Installation (M12) BMT 965 ST / BT – Installation (M8) Network Operation Appendix H: MODBUS MODBUS RTU...
  • Page 5: General Description

    BMT 965 Link. Excel can open the CSV concentration log di- rectly on the BMT 965, because the instrument will show up on the PC as an external drive when connected via USB, allowing simple copy action of stored files using Windows Explorer without installing any additional software or drivers.
  • Page 6: Cautions & Warnings

    Dispose lamp at a waste disposal place which is qualified to handle mercury containing lamps. If you cannot find a respective place, return the lamp to BMT MESSTECHNIK GMBH. Warning: Before opening the sample gas filter make sure that the sample line does not contain ozone gas, and is not under an overpressure.
  • Page 7: Précautions

    Précautions Avertissement : L’ozone est un gaz à forte toxicité. Les concentrations d’ozone mesurées à l’aide de l’analyseur d’ozone BMT 965 vont au-delà de la limite mortelle. C’est pourquoi il convient d’utiliser une technique de sécurité adéquate (détecteur d’ozone). Avertissement : Ce produit présuppose une installation électrique en bâtiment qui assure la protection contre les surintensités et contre les courts-circuits.
  • Page 8: Installation And Power Connection

    Installation and Power Connection The OZONE ANALYZER BMT 965 is a 144 x 72 mm front panel instrument (according to DIN 61554). For additional information on other variants of the BMT 965 (AQ, Cabinet etc.) con- sult the appropriate appendix of this manual.
  • Page 9 OZONE ANALYZER BMT 965 Manual, Rev. 01/2024 Warning: This product relies on the building's installation for short-circuit (overcurrent) protec- tion. Ensure that a fuse or circuit breaker no larger than 15 A at 120 VAC (10 A at 240 VAC) is used on the phase conductor.
  • Page 10: Photometers And Dirt

    BMT ozone analysers for gaseous ozone are equipped with particle filters containing a replaceable filter insert. The filter inserts should from time to time be checked for dirt (see page 52, Mainte- nance), and be replaced on a regular basis depending on the degree of particle content of the sample gas.
  • Page 11 OZONE ANALYZER BMT 965 Manual, Rev. 01/2024 ___________________________________________________________________________...
  • Page 12: Output And Control Terminals

    The binary input is a control input used to trigger the ZERO function of the OZONE ANALYZER BMT 965. By applying a voltage of typically +24 VDC between pin 11 (+) and pin 10 (-) for about 0.5 seconds the instrument will be zeroed. The ZERO function may be...
  • Page 13: Binary Outputs

    OZONE ANALYZER BMT 965 Manual, Rev. 01/2024 Input current at the binary input is approx. 8 mA. The input is protected against voltages with wrong polarity. Binary Outputs The binary outputs are relay contacts, which are used to signal errors and alarms. An additional contact can be used for the selection of purge gas during automatic zeroing.
  • Page 14: Usb-Interface

    It is very important to really make sure that no ozone is present in the cuvette during zero- ing! Before zeroing the BMT 965 has to be purged with oxygen or filtered air. ___________________________________________________________________________...
  • Page 15: Automatic Zeroing With Control Of Purge Gas

    Automatic Zeroing with Control of Purge Gas Purge gas control can be taken over by the BMT 965. The relay contact Purge (Pin 2) is used for this purpose. This contact (max. 28 V, 0.5 A) can switch an ozone proof solenoid valve to switch from ozone to an ozone free gas like CDA (Compressed Dry Air) or Oxygen.
  • Page 16: Front Panel Operation

    In case the OZONE ANALYZER BMT 965 is equipped with an Internal Purge Unit (solenoid valve and air pump with particle filter) as an option, e.g. in the model BMT 965 BT (see Appen- dix B) the terminal 2 should not be connected externally.
  • Page 17: Changing Parameters

    OZONE ANALYZER BMT 965 Manual, Rev. 01/2024 The pushbuttons can be used to perform the following operations:  Switch to pressure display (and back)  Zero the BMT 965  View parameters  Change parameters  Confirm file copy or firmware upgrade...
  • Page 18: Zeroing The Instrument From The Front Panel

    ZERO button may be pressed again, after which zeroing starts. Further information about zeroing the BMT 965 can be found on page 14. The Menu View Parameters In the menu View Parameters the configuration of the BMT 965 can be viewed, but it cannot be changed. ___________________________________________________________________________...
  • Page 19 OZONE ANALYZER BMT 965 Manual, Rev. 01/2024 View Parameters (1) View Parameters (2) *Available from firmware version 1.05 The following parameters are shown:  Units Unit of ozone concentration Unit of pressure ___________________________________________________________________________...
  • Page 20: The Menu Set Parameters

    OZONE ANALYZER BMT 965 Manual, Rev. 01/2024  Alarms Activation, thresholds, latching, closing or opening of Alarm Relays  RS-232 Baud rate, periodic transmission or polling, time interval of periodic transmission  Gas-Parameters Nature of the carrier gas: normalizing conditions, air or oxygen (incl. PSA oxygen) ...
  • Page 21 2 seconds. The configuration of the BMT 965 can be changed here. The diagram shows the selectable param- eters. In order to change a setting, the ENTER button has to be pressed. Logical variables, as e.g.
  • Page 22: Units

    OZONE ANALYZER BMT 965 Manual, Rev. 01/2024 One more example: the numerical parameter High Alarm - Threshold (determines the threshold, above which a High Alarm occurs) shall be changed from 75 g/Nm to 90 g/Nm Button Display 0.00 g/Nm SCROLL 1.013 bar...
  • Page 23: Pressure

    OZONE ANALYZER BMT 965 Manual, Rev. 01/2024  %wt(air) (carrier gas air) If the concentration unit is changed the range will change, too: g/Nm % wt/wt or Range-ID (g/m , ppm %wt(air) 2.000 0.1500 1000 5.000 0.3500 2500 10.00 0.7000 5000 20.00...
  • Page 24: Alarms

    OZONE ANALYZER BMT 965 Manual, Rev. 01/2024 Alarms High-Alarm This alarm occurs if Enable/Disable is activated and the limit stored under Threshold is exceeded. In case Relays Open/Close is set to Relays Opening, the High-Alarm-Relay opens (default) , otherwise it closes. At the same time a High- Alarm-Event is entered into the Event-Log.
  • Page 25: Input/Output

    For test purposes both analog outputs can be set to their max. (10 V / 20 mA) re- spectively min. (0 V / 4 mA) values. With the program BMT 965 Link any voltage and current can be put out.
  • Page 26: Date

    OZONE ANALYZER BMT 965 Manual, Rev. 01/2024 Date During entry the date will be constantly tested on conformance to the calendar rules, so it is not possible for example to enter the date 29.02.18. In order to make this test possible, first the year, then the month and then the day has to be set.
  • Page 27: Reset Parameters

    If Timed/Polled is set to Timed, there is an output every Time Interval seconds (s. configuration of the RS-232 on page 25). In case Polled is set, the BMT 965 expects the input of a question mark ('?', without CR), to which it responds with a block of data. User mode data output always follows the format in the following example: 26.03.18,12:16:28,154.3 g/Nm3,1.008 bar,00.0,0000...
  • Page 28: Link-Mode

    Communication in Link-Mode always obeys the following format. All communication has to be initiated from the outside: *Command Number#[optional parameter] The BMT 965 always responds after completion of the instruction with *Command Number#[optional parameter] The optional parameter can have different decimally coded formats: ...
  • Page 29: File Operations And The Usb Interface

    OZONE ANALYZER BMT 965 Manual, Rev. 01/2024 It is very important to wait for confirmation from the BMT 965 once a command is sent. Link- Mode is started by sending the following command: *0#DL4EBY The BMT 965 responds with *0#DL7ZN The User-Mode described above is now deactivated.
  • Page 30: Connecting A Usb Flash Drive To The Bmt 965

    Copy files? Pressing BACK aborts. If you press ENTER, all log files in internal storage are copied into a folder BMT. If such a folder does not exist, it will be created. Copy progress is shown on the display. Old ___________________________________________________________________________...
  • Page 31: Firmware Upgrade

    Update progress is shown. It can take up to two minutes. When the display shows Remove USB Flash remove the host adapter. As soon as the host adapter is removed, the BMT 965 goes through a restart with warm-up. During warm-up, no measurements are made and outputs are in warm-up state as described in section 5.
  • Page 32: 10 Error Handling And Early Warnings

    10 Error Handling and Early Warnings The BMT 965 has diverse possibilities to recognize errors, to signal them and to early-warn against them. Errors and Early Warnings are displayed on the front panel. Depending on the importance of the error, the Error Relay (pins 1 and 3) as well as the Early Warning contacts Lamp Low (Pin 9) or Cuvette Dirty (Pin 14) are activated (opened).
  • Page 33: Lamp High Error

    The lamp contains significantly less than 5 milligrams of mercury. Mercury is a poison. Dispose lamp at a waste disposal place which is qualified to handle mercury containing lamps. If you cannot find a respective place, return the lamp to BMT. Cuvette Dirty Warning In each zeroing the dirtiness of the cuvette is measured and displayed.
  • Page 34: Low Pressure Error

    11 Event- and Error-Log These two logs are stored by the BMT 965 on the internal SD card and document important events and errors. Memory capacity is not limited. New entries are appended as they arrive. Both logs can be read out via USB to a computer and can be copied directly to a flash drive.
  • Page 35: 12 Concentration Logs

    13 The Program BMT 965 Link On the SD card which is delivered with the instrument you will find the Windows program BMT 965 Link, which is using the Link Mode as described on page 28, and in Appendix A. It has ___________________________________________________________________________...
  • Page 36 The Save and Load functions in the main menu under File are used to save configurations of the BMT 965 onto your PC and load it again at a later time. This helps configuring all analysers with identical settings in multiple locations of one project.
  • Page 37: 14 Maintenance

    OZONE ANALYZER BMT 965 Manual, Rev. 01/2024 14 Maintenance Maintenance is limited to a regular check of the sample gas input filter. The pure white material easily displays any dirt (except if it is white). A tool is provided to open the filter holder.
  • Page 38: 15 Troubleshooting

    The logging capabilities of the software and the instru- ment can also be used to detect randomly occurring errors. In case the BMT 965 has to be sent in for service or repair, you do not need an RMA, but please provide the following details:...
  • Page 39: 16 Specifications

    (IPU) or external pump and solenoid valve (not included) software BMT 965 Link, instrument configuration and readout of Event, Error and Concentration Logs on a Windows PC power wide range input: 100 - 240 VAC, 50/60 Hz, 15 VA optional: 12 –...
  • Page 40: Appendix A: Link-Mode Commands

    Appendix A: Link-Mode Commands The following table describes all available Link-Mode commands for the serial interface. Com- mands with question marks retrieve information from the BMT 965. Caution: This set of commands should only be used by programmers who have a good under-...
  • Page 41 OZONE ANALYZER BMT 965 Manual, Rev. 01/2024 Meaning PC->965 965->PC Concentration? *9#float,byte float: Concentration byte: Unit: 0: g/Nm 1: %wt/wt 2: ppm 3: g/m 4: ppm 5: %wt Pressure? *10# *10#float,byte = float * Multiplier float: Pressure always in bar byte Multiplier: 0: 1.0...
  • Page 42 OZONE ANALYZER BMT 965 Manual, Rev. 01/2024 Meaning PC->965 965->PC Normalizing pressure? *23# *23#float,byte = float x Multiplier float: Pressure always in bar byte Multiplier: 0: 1.0 (Unit bar) 1: 14.50778 (Unit psi) 2: 750.0617 (Unit Torr) 3: 0.1 (Unit MPa)
  • Page 43 OZONE ANALYZER BMT 965 Manual, Rev. 01/2024 Meaning PC->965 965->PC Alarm Beep? *46# *46#byte 1: On 0: Off Set Alarm Beep *47#byte *47# 1: On 0: Off Cuvette Status? *48# *48#float float: % Dirty 0: Clean Trigger Zero (Parameter for security) *83#3.14159...
  • Page 44 OZONE ANALYZER BMT 965 Manual, Rev. 01/2024 Meaning PC->965 965->PC Get Errors (full, binary coded): *121# *121#word Bit 0: Lamp Low Warning Bit 1: Lamp Low Error Bit 2: Lamp Off Error Bit 3: Cuvette Dirty Warning Bit 4: Cuvette Dirty Error...
  • Page 45: Appendix B: Bench Top Version Bmt 965 Bt

    Operation The basic operation of the BMT 965 BT is the same as of the standard BMT 965, see chapters 1 - 14 for more details. Care must be taken using the Catalyzing Cartridge, which may never be exposed to water or humidity, as this might damage the catalysing material.
  • Page 46: Specifications (Bmt 965 Bt Only)

    The BMT 965 BT may be ordered together with a soft carrying bag for protecting the instrument during transport. The bag has room enough for accessories like filter inserts for the sample gas filter, a tool to open the filter holder and FEP connecting tubing.
  • Page 47: Appendix C: Cabinet Version Bmt 965C

    Appendix C: Cabinet Version BMT 965C General description The OZONE ANALYZER BMT 965C (cabinet version) is housed in a splash-proof IP 65 (NEMA 4X) aluminium cabinet. It is NRTL safety certified by TUV Rheinland of North America. It is also certified according to IACS E10 and USCG 46 CFR 612.060-30 for operation in ballast water treatment systems on ships.
  • Page 48: Ozone Destruct

    OZONE ANALYZER BMT 965 Manual, Rev. 01/2024 For sample gas connection 3x5 mm FEP (or 1/8'' x 3/16'' FEP) tubing should be used, which will be supplied on request. Warning: Do not apply more than the rated gas pressure (pressure range) to the instrument! The Cabinet is also available with fittings for 4x6 mm FEP tubing, or Swagelok fittings (1/8"...
  • Page 49: Electric Connections

    OZONE ANALYZER BMT 965 Manual, Rev. 01/2024 Caution: If the generator feed gas contains nitrogen, connect a tube to the outlet of the ozone destruct to lead away the vent gas. Corrosive nitric acid will be formed when vent gas comes in contact with the moist ambient air.
  • Page 50 OZONE ANALYZER BMT 965 Manual, Rev. 01/2024 orange two pole connector on the PCB. Give enough slack on the PE (Protective Ground ) to ensure that, if the strain relief of the cable gland should fail, the power carrying wires are disconnected first.
  • Page 51: Two-Stage Particle Filter

    For maintenance on the sample gas filter see chapter Maintenance on the next page. Operation The basic operation of the BMT 965 C is the same as of the standard BMT 965, see chapters 1 to 14 for details. Adjustment of Sample Flow: The sample gas flow rate can be set with the red knob (door open, upper right corner).
  • Page 52: Maintenance

    OZONE ANALYZER BMT 965 Manual, Rev. 01/2024 Note: Setting the Auto Zero Interval to zero hours also means, that the analyser does not go through the purge cycle and does not activate the Purge Unit! In this case, the user shall never initiate zeroing with ozone applied to the inlet of the Cabinet.
  • Page 53: Specifications (Bmt 965 C Only)

    (W x H x D) 300 x 200 x 120 mm weight 3.6 kg compliance CE-marked (EMC & safety), cTUVus NRTL-listed (safety), USCG 46 CFR 612.060-30 General specifications not specific to the BMT 965 C are found on page 39. ___________________________________________________________________________...
  • Page 54: Appendix D: Ozone-In-Off-Gas System

    SGP5, the flow meter FM82, and the DH6 power supply, in a wall mounted aluminum cabinet, 300 x 400 x 120 mm (W x H x D, twice the height of the standard BMT 965C cabinet). The dryer DH6 is mounted upright on top of the reaction vessel, or a large diameter off-gas tube.
  • Page 55: Off-Gas Cabinet Bmt 965 Og

    OZONE ANALYZER BMT 965 Manual, Rev. 01/2024 Off-Gas Cabinet BMT 965 OG As the recommended configuration the cabinet contains the UV photometric ozone analyser, a long-life ozone resistant sample gas pump SGP5, the power supply for the external Peltier-electric cooler/dryer DH6, a purge unit (solenoid valve/air pump assembly with particle filter) for fully...
  • Page 56 The DH6 electric cooler/dryer and the analyser cabinet BMT 965 OG are connected by an electric cable, and two FEP tubings 3x5 mm leading the sample gas from the reactor to the analyser for ozone measurement, and leading it back to the reactor after measurement (no critical ozone de- struct necessary).
  • Page 57: Electric Connections

    OZONE ANALYZER BMT 965 Manual, Rev. 01/2024 In the tubing line from the reactor to the Off-Gas Cabinet an optional Dirt Trap DT 100 can be provided for safety, and to watch the sample gas after its passage through the sample gas cooler/dryer.
  • Page 58 OZONE ANALYZER BMT 965 Manual, Rev. 01/2024 Connect the power carrying wires to the orange two pole female plug labeled “L” and “N” which came with the instrument. Attach these wires to each other with a cable tie tightly behind the orange two pole female plug.
  • Page 59: Operation

    OZONE ANALYZER BMT 965 Manual, Rev. 01/2024 Operation The basic operation of the Off-Gas Cabinet is the same as of the standard BMT 965 ST, see chap- ters 1 to 14 for details! Adjustment of Sample Flow: The sample gas flow is produced by the sample gas pump SGP5, and is set in the factory.
  • Page 60: Specifications (Bmt 965 Og Only)

    6.5 kg (main cabinet) 1.5 kg (dryer DH6) compliance CE-marked (EMC & safety), cTUVus NRTL-listed (safety), USCG 46 CFR 612.060-30 General specifications not specific to the BMT 965 OG are found on page 39. contact without function if option not installed ___________________________________________________________________________...
  • Page 61: Appendix E: Di Water Version Bmt 965 Aq

    BMT 965ST for the measurement of ozone in gas. The BMT 965 AQ is a SENSOR because it does not have a display. It is designed to directly be connected to e.g. a workstation via a 4-20 mA, or 0-10 V, signal line. The workstation also has to monitor and control the instrument's functions like auto-zeroing, or possible failure indications.
  • Page 62 Zeroing has to be initiated by pressing the push button ZERO at the optional REMOTE DISPLAY BMT 965 RD, or via the binary input at pins 5 and 6 of the signal connector, or RS-232, or USB (for details see the main part of the manual). Prior to zeroing the analyser, it has to be assured that the cuvette is filled with water having zero ozone concentration.
  • Page 63: Electric Connections

    For further description of the functions and properties of the OZONE-IN-WATER SENSOR BMT 965 AQ refer to the main part of the manual. Electric connections Note: The signal connector pinout of the BMT 965 AQ is different to the that of the BMT 965 ST! Signal connector: current signal, output...
  • Page 64: Specifications (Bmt 965 Aq Only)

    12 - 36 VDC, 15 W dimensions (W x H x D) 260 x 160 x 91 mm weight 3.0 kg General specifications not specific to the BMT 965 AQ and BMT 965 AQ/HF are found on page 39. ___________________________________________________________________________...
  • Page 65: Appendix F: Remote Display Bmt 965 Rd

    REMOTE DISPLAY. The REMOTE DISPLAY BMT 964 RD is fully compatible with the BMT 965 series of analysers. In addition, the REMOTE DISPLAY BMT 965 RD may be used on the BMT 964 series of ana- lysers.
  • Page 66: Appendix G: Ip-Based Communication

    100 m. The MAC address of the device will be in a range from 70-B3-D5-5D-60-00 to 70-B3-D5-5D-6F-FF, as assigned to BMT MESSTECHNIK by the IEEE. The IP address of the device can be either assigned dynamically by DHCP or it can be configured as a static address.
  • Page 67: Bmt 965 St / Bt - Installation (M8)

    Network Operation A new BMT 965 comes with its DHCP client enabled. IP address, gateway and netmask will be autoconfigured by the DHCP server on the network, as soon as the instrument is connected or powered on. A BMT 965 with a networking option provides the additional display menu “View Network”, where the IP address can be seen.
  • Page 68: Appendix H: Modbus

    MODBUS enables a SCADA system to have direct access to all relevant parameters (e.g. concen- tration, pressure, cuvette status) and all alarms of the BMT 965. It is also possible to set some parameters like Low and High Alarm Limits and to execute a zero command. Additionally, Modbus diagnostic information can be requested.
  • Page 69: Modbus/Tcp

    1 … 247 MODBUS/TCP The BMT 965 C, BMT 965 OG, BMT 965 AQ, BMT 965 ST and BMT 965 BT are available with a MODBUS/TCP option. Such an instrument will provide a MODBUS/TCP server, listening on the MODBUS standard port 502. The operation conforms to the document: MODBUS MESSAGING ON TCP/IP IMPLEMENTATION GUIDE V1.0b...
  • Page 70 The instrument will then check query data, and, if invalid data is detected, will respond with a MODBUS Exception. Caution: Care has to be taken that the MODBUS client does not reconfigure the BMT 965 in an endless loop. The internal non-volatile memory will only tolerate a limited (1,000,000) number of write cycles.
  • Page 71 OZONE ANALYZER BMT 965 Manual, Rev. 01/2024 UINT32 32-bit unsigned integer stored in 2 sequential registers, each 0 … 4 294 967 295 big endian coded The lower signification word is hold in the lower register, then the higher significant.
  • Page 72 OZONE ANALYZER BMT 965 Manual, Rev. 01/2024 Big Endian High Word Serial Number UINT32 Big Endian 03 (0x03) Low Word 04 (0x04) * Big Endian High Word Ozone Unit UINT16 Big Endian R/W* 0: g/Nm3 03 (0x03) 1: %wt/wt 04 (0x04) *...
  • Page 73 OZONE ANALYZER BMT 965 Manual, Rev. 01/2024 * This function requires firmware version 1.05 or higher. Register Map – FC 16 (0x10) For backward compatibility to legacy BMT 964 and BMT 965 V1.04 or below Regis- Reg- Data Byte/Word Function...
  • Page 74 OZONE ANALYZER BMT 965 Manual, Rev. 01/2024 Write Coil Map – FC 05 (0x05), 16 (0x10) Coil Description Comment Low Alarm Enabled Write Single Coil (FC 05) is used to force a single output to ei- ther ON or OFF. The requested state is specified by a constant: High Alarm Enabled ON –...

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